Exploiting amphiphilicity: facile metal free access to thianthrenes and related sulphur heterocycles.
نویسندگان
چکیده
Benzodithioloimines are reacted with arynes or alkynes substituted with electron-withdrawing groups to afford the corresponding thianthrene or benzo[b][1,4]dithiine derivatives. The transformation takes place under mild reaction conditions without any transition metal. Furthermore, the reaction mode could be expanded to 2-thiocyanatopyrroles yielding pyrrolothiazoles.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 44 شماره
صفحات -
تاریخ انتشار 2015