Exploiting amphiphilicity: facile metal free access to thianthrenes and related sulphur heterocycles.

نویسندگان

  • Martin Pawliczek
  • Lennart K B Garve
  • Daniel B Werz
چکیده

Benzodithioloimines are reacted with arynes or alkynes substituted with electron-withdrawing groups to afford the corresponding thianthrene or benzo[b][1,4]dithiine derivatives. The transformation takes place under mild reaction conditions without any transition metal. Furthermore, the reaction mode could be expanded to 2-thiocyanatopyrroles yielding pyrrolothiazoles.

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عنوان ژورنال:
  • Chemical communications

دوره 51 44  شماره 

صفحات  -

تاریخ انتشار 2015